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The add of a new soil or a new tracer takes place in cs_user_model (see Settings related to the groundwater flow module with CDO/HHO schemes for more details).
Example for a saturated soil defined by an isotropic permeability.
cs_gwf_set_aniso_saturated_soil sets a saturated soil defined by an anisotropic permeability. Soils which behave according to a Van Genuchten model can be specified using cs_gwf_set_aniso_genuchten_soil or cs_gwf_set_iso_genuchten_soil. More advanced definition using a user-defined model is also possible using cs_gwf_set_user_soil.
Here is an example for a standard tracer.